Pressure of Hydrogen Gas Formula:
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Definition: This calculator determines the pressure of dry hydrogen gas collected over water by subtracting the water vapor pressure from the total atmospheric pressure.
Purpose: It's essential for chemistry experiments where hydrogen gas is collected by water displacement, helping researchers obtain accurate pressure measurements.
The calculator uses Dalton's Law of Partial Pressures:
Where:
Explanation: The total pressure in the collection vessel equals the sum of the partial pressures of hydrogen gas and water vapor.
Details: Correct hydrogen pressure measurement is crucial for stoichiometric calculations, gas law applications, and determining reaction yields in chemical experiments.
Tips: Enter the atmospheric pressure (typically 760 mmHg at sea level) and water vapor pressure (default 18.6 mmHg at 20°C). Ensure atmospheric pressure > water vapor pressure.
Q1: Why do we subtract water vapor pressure?
A: Because the collected gas is a mixture of hydrogen and water vapor, we need to isolate the hydrogen's partial pressure.
Q2: How do I find water vapor pressure?
A: It depends on temperature - use standard tables (default is 18.6 mmHg at 20°C). Higher temperatures increase water vapor pressure.
Q3: What units should I use?
A: mmHg (millimeters of mercury) is standard, but any consistent pressure units will work in the calculation.
Q4: What if my atmospheric pressure is in other units?
A: Convert to mmHg first (1 atm = 760 mmHg, 1 kPa = 7.50062 mmHg).
Q5: When would this calculation be used?
A: Primarily in lab experiments where hydrogen gas is collected over water, such as metal-acid reactions or electrolysis.