Vapor Pressure Formula (Raoult's Law for mixtures):
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Definition: This calculator estimates the vapor pressure of a solution based on the vapor pressures of its components and their mole fractions using Raoult's Law.
Purpose: It helps chemists, engineers, and students determine the vapor pressure of mixtures, which is important for understanding evaporation rates, boiling points, and phase behavior.
The calculator uses Raoult's Law formula:
Where:
Explanation: The total vapor pressure is the sum of each component's pure vapor pressure multiplied by its mole fraction in the liquid.
Details: Vapor pressure determines a liquid's evaporation rate, affects boiling points, and is crucial for distillation processes, chemical reactions, and environmental studies.
Tips: Enter the vapor pressure and mole fraction for each component. For binary mixtures, x₂ will automatically calculate as (1 - x₁) if left empty. All mole fractions must be between 0 and 1.
Q1: What is Raoult's Law?
A: Raoult's Law states that the vapor pressure of an ideal solution depends on the vapor pressure of each component and its mole fraction.
Q2: When is Raoult's Law valid?
A: For ideal solutions where intermolecular forces between different molecules are similar to those between like molecules.
Q3: What if my solution is non-ideal?
A: For non-ideal solutions, you would need activity coefficients or other models like Henry's Law for dilute solutions.
Q4: How do I find pure component vapor pressures?
A: They can be found in chemical handbooks or calculated using Antoine equation if temperature is known.
Q5: Can I calculate for more than two components?
A: This calculator handles up to two components, but Raoult's Law can be extended to any number of components.